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Title: Kinetics of the reaction of CF3 with O2 over the temperature range 233-273 K
Journal: Chem. Phys. Lett.
Volume: 129
Page(s):
Year: 1986
Reference type: Journal article
Squib: 1986CAR/LES433
Reaction:
·CF3 + O2 → CF3O2
Reaction order:
3
Temperature:
232 - 373
K
Pressure: 1.33E-3 - 1.33E-2 bar
Rate expression:
1.9x10-29 [cm6/molecule2 s] (T/298 K)(-4.70±0.42)
Bath gas:
N2
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm6/molecule2 s] |
|---|---|
| 232 | 6.16E-29 |
| 250 | 4.34E-29 |
| 275 | 2.77E-29 |
| 300 | 1.84E-29 |
| 325 | 1.26E-29 |
| 350 | 8.92E-30 |
| 373 | 6.61E-30 |