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Accessibility information
Author(s):   Forst, W.; Caralp, F.
Title:   Microcanonical variational theory of radical recombination by inversion of interpolated partition function. Part 2 - CX3 + O2 (X = H, F, Cl)
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   87
Page(s):   2307 - 2315
Year:   1991
Reference type:   Journal article
Squib:   1991FOR/CAR2307-2315

Reaction:   ·CF3 + O2CF3O2
Reaction order:   2
Temperature:   233 - 373 K
Rate expression:   6.34x10-12 [cm3/molecule s] (T/298 K)-0.27
Bath gas:   N2
Category:  Experiment
Data type:   RRK(M) extrapolation

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
233 6.78E-12
250 6.65E-12
275 6.48E-12
300 6.33E-12
325 6.20E-12
350 6.07E-12
373 5.97E-12