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Title: Rate constants and atmospheric lifetimes for the reactions of OH radicals and Cl atoms with haloalkanes
Journal: Int. J. Chem. Kinet.
Volume: 25
Page(s): 273 - 284
Year: 1993
Reference type: Journal article
Squib: 1993DON/SHA273-284
Reaction:
tert-C4H9Cl + ·Cl → HCl + (CH3)2CClCH2
Reaction order:
2
Reference reaction:
C2H6 + ·Cl → ·C2H5 + HCl
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
1.3x10-11 [±3.99x10-12 cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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