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Author(s):   Ashford, R.D.; Ogryzlo, E.A.
Title:   Arrhenius parameter for some gas-phase cycloaddition reactions of singlet molecular oxygen
Journal:   Can. J. Chem.
Volume:   52
Year:   1974
Reference type:   Journal article
Squib:   1974ASH/OGR3544

Reaction:   O2(1DELTA) + 2-Methylfuran → Products
Reaction order:   2
Temperature:   300 - 550 K
Pressure:  3.33E-3 bar
Rate expression:   3.32x10-13 [cm3/molecule s] e-16296 [±8314472 J/mole]/RT
Uncertainty:   1.5800000429153442
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Mass spectrometry

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 4.83E-16
325 7.98E-16
350 1.23E-15
375 1.78E-15
400 2.47E-15
425 3.30E-15
450 4.26E-15
475 5.36E-15
500 6.59E-15
525 7.94E-15
550 9.41E-15