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Title: Elimination kinetics and mechanisms for several 2-alkoxyacetic acids in the gas phase
Journal: J. Phys. Org. Chem.
Volume: 9
Page(s): 787 - 794
Year: 1996
Reference type: Journal article
Squib: 1996CHU/ROT787-794
Reaction:
CH3OCH2COOH → CH2O + CH3OH + CO
Reaction order:
1
Temperature:
379 - 410
K
Pressure: 7.60E-3 - 0.35 bar
Rate expression:
1.26x1012 [s-1] e-192896 [±1929 J/mole]/RT
Uncertainty:
2.08999991
Bath gas:
Cyclohexene
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 379 | 3.28E-15 |
| 400 | 8.15E-14 |
| 410 | 3.35E-13 |