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Author(s):   Kalra, B.L.; Cho, J.Y.; Lewis, D.K.
Title:   Kinetics of the thermal isomerization of methylcyclopropane
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   362 - 364
Year:   1999
Reference type:   Journal article
Squib:   1999KAL/CHO362-364

Reaction:   MethylcyclopropaneIsobutene
Reaction order:   1
Temperature:   695 - 1150 K
Pressure:  6.00E-2 - 1.00E-1 bar
Rate expression:   6.46x1014 [s-1] e-277703 [±840 J/mole]/RT
Uncertainty:   1.12
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
695 8.69E-7
700 1.23E-6
725 6.35E-6
750 2.95E-5
775 1.24E-4
800 4.77E-4
825 1.69E-3
850 5.56E-3
875 1.71E-2
900 4.93E-2
925 1.34E-1
950 3.48E-1
975 8.57E-1
1000 2.02E0
1025 4.56E0
1050 9.90E0
1075 2.07E1
1100 4.20E1
1125 8.25E1
1150 1.57E2