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Author(s):   Anderson, R.S.; Huang, L.; Iannone, R.; Thompson, A.E.; Rudolph, J.
Title:   Carbon kinetic isotope effects in the gas phase reactions of light alkanes and ethene with the OH radical at 29±
Journal:   J. Phys. Chem. A
Volume:   108
Page(s):   11537 - 11544
Year:   2004
Reference type:   Journal article
Squib:   2004AND/HUA11537-11544

Reaction:   iso-C4H10 + ·OH → Products
Reaction order:   2
Temperature:   296 K
Pressure:  1.01 bar
Rate expression:   2.0x10-12 [±2.0x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   Carbon-13 kinetic isotope effects were also determined. Uncertainty in the rate constant is the error of the mean.

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