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Wilson, E.W.; Hamilton, W.A.; Kennington, H.R.; Evans, B.; Scott, N.W.; DeMore, W.B.
Measurement and estimation of rate constants for the reactions of hydroxyl radical with several alkanes and cycloalkanes
J. Phys. Chem. A
3593 - 3604
iso-C4H10 + ·OH → Products
229 - 403
Pressure: 1.01 bar
3.18x10-12 [cm3/molecule s] (T/298 K)1.12 e-1013 [J/mole]/RT
Relative rate value measured
Static or low flow - Data taken vs time
By end product analysis
OH generated by 185-nm photolysis of H2O for most measurements above 0 C and by photolysis of N2O/H2 mixtures for low-temperature measurements. Good agreement reported in the overlap region, but above room temperature, rate constants from the N2O/H2 system were higher than for the H2O system, and were not used.
Rate constant measured relative to OH + n-butane (k = 1.68x10-11exp(-584/K) cm3s-1.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
|T (K)||k(T) [cm3/molecule s]|