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Author(s):   Sivaramakrishnan, R.; Michael, J.V.
Title:   Rate Constants for OH with Selected Large Alkanes: Shock-Tube Measurements and an Improved Group Scheme
Journal:   J. Phys. Chem. A
Volume:   113
Page(s):   5047 - 5060
Year:   2009
Reference type:   Journal article
Squib:   2009SIV/MIC5047-5060

Reaction:   iso-C4H10 + ·OH → Products
Reaction order:   2
Temperature:   298 - 2000 K
Rate expression:   5.93x10-13 [cm3/molecule s] (T/298 K)2.41 e3168 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Rate constants calculated using a group reactivity scheme devised in this work.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 2.13E-12
300 2.14E-12
400 3.13E-12
500 4.43E-12
600 6.06E-12
700 8.02E-12
800 1.03E-11
900 1.30E-11
1000 1.61E-11
1100 1.96E-11
1200 2.35E-11
1300 2.78E-11
1400 3.26E-11
1500 3.78E-11
1600 4.35E-11
1700 4.96E-11
1800 5.62E-11
1900 6.34E-11
2000 7.10E-11