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Title: Kinetic studies on reactions of NCO(X«Pi»i) with alcohol molecules
Journal: Chem. Phys. Lett.
Volume: 381
Page(s): 199 - 204
Year: 2003
Reference type: Journal article
Squib: 2003PEI/HU199-204
Reaction:
1-C5H11OH + NCO → Products
Reaction order:
2
Temperature:
298
K
Pressure: 1.33E-2 bar
Rate expression:
2.33x10-12 [±5.3x10-13 cm3/molecule s]
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
None reported
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
NCO radical was generated by the reaction of CH with NO, where CH was produced by the
photolysis of CHBr3 at 266 nm. An YAG pumped dye laser was used to electronically excite the NCO at 438.6 nm and the decays of the resulting LIF signal were followed in real time to determine the kinetics.
The reaction mechanism is thought to be H abstraction.
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