Author(s):   Kerr, J.A.; Smith, B.J.A.; Trotman-Dickenson, A.F.; Young, J.C.
Title:   The abstraction of halogen atoms from alkyl halides by the trichlorosilyl radical
Journal:   J. Chem. Soc. A
Page(s):   510 - 513
Year:   1968
Reference type:   Journal article
Squib:   1968KER/SMI510-513

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1968KER/SMI510-513	CH₃Br + SiCl₃ → ·CH₃ + Silane, bromotrichloro-	373 - 573	0.27	-2.25E04		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	C₂H₅Br + SiCl₃ → ·C₂H₅ + Silane, bromotrichloro-	373 - 573	0.13	-2.67E04		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	C₂H₅Br + SiCl₃ → ·C₂H₅ + Silane, bromotrichloro-	387 - 521	0.21	1.31E04		2
Reference reaction: tert-C₄H₉Cl + SiCl₃ → tert-C₄H₉ + SiCl₄					2
1968KER/SMI510-513	C₂H₅Cl + SiCl₃ → ·C₂H₅ + SiCl₄	373 - 573	0.94	-4681		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Br + SiCl₃ → Other Products + 2-C₃H₇	373 - 573	0.53	-2.94E04		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Br + SiCl₃ → 2-C₃H₇ + Silane, bromotrichloro-	374 - 493	1.96	-6901		2
Reference reaction: CH₃Br + SiCl₃ → Other Products + ·CH₃					2
1968KER/SMI510-513	iso-C₃H₇Br + SiCl₃ → 2-C₃H₇ + Silane, bromotrichloro-	373 - 573	0.53	1.48E07		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Br + SiCl₃ → 2-C₃H₇ + Silane, bromotrichloro-	379 - 545	1.58	-2777		2
Reference reaction: C₂H₅Br + SiCl₃ → Other Products + ·C₂H₅					2
1968KER/SMI510-513	iso-C₃H₇Cl + SiCl₃ → 2-C₃H₇ + SiCl₄	386 - 521	1.76	-3176		2
Reference reaction: C₂H₅Cl + SiCl₃ → ·C₂H₅ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Cl + SiCl₃ → 2-C₃H₇ + SiCl₄	402 - 536	0.91	457		2
Reference reaction: sec-C₄H₉Cl + SiCl₃ → sec-C₄H₉ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Cl + SiCl₃ → 2-C₃H₇ + SiCl₄	376 - 566	1.25	-2586		2
Reference reaction: 1-C₄H₉Cl + SiCl₃ → 1-C₄H₉ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Cl + SiCl₃ → 2-C₃H₇ + SiCl₄	350 - 4620	1.03	5729		2
Reference reaction: tert-C₄H₉Cl + SiCl₃ → tert-C₄H₉ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Cl + SiCl₃ → 2-C₃H₇ + SiCl₄	370 - 566	1.45	-2336		2
Reference reaction: iso-C₄H₉Cl + SiCl₃ → iso-C₄H₉ + SiCl₄					2
1968KER/SMI510-513	iso-C₃H₇Cl + SiCl₃ → 2-C₃H₇ + SiCl₄	361 - 525	1.78	-1754		2
Reference reaction: t-C₄H₉CH₂Cl + SiCl₃ → Neopentyl + SiCl₄					2
1968KER/SMI510-513	sec-C₄H₉Cl + SiCl₃ → sec-C₄H₉ + SiCl₄	373 - 573	1.82	-8314		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	1-C₄H₉Cl + SiCl₃ → 1-C₄H₉ + SiCl₄	373 - 573	1.32	-5271		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	tert-C₄H₉Br + SiCl₃ → tert-C₄H₉ + Silane, bromotrichloro-	373 - 573	0.64	-3.32E04		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	tert-C₄H₉Br + SiCl₃ → tert-C₄H₉ + Silane, bromotrichloro-	378 - 484	1.20	-3700		2
Reference reaction: iso-C₃H₇Br + SiCl₃ → Other Products + 2-C₃H₇					2
1968KER/SMI510-513	tert-C₄H₉Cl + SiCl₃ → tert-C₄H₉ + SiCl₄	373 - 573	1.60	-1.36E04		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	tert-C₄H₉Cl + SiCl₃ → tert-C₄H₉ + SiCl₄	373 - 573	1.65	-7865		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	iso-C₄H₉Cl + SiCl₃ → iso-C₄H₉ + SiCl₄	376 - 549	1.14	-5.52E06		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2
1968KER/SMI510-513	t-C₄H₉CH₂Cl + SiCl₃ → Neopentyl + SiCl₄	373 - 573	0.93	-6103		2
Reference reaction: CH₃Cl + SiCl₃ → ·CH₃ + SiCl₄					2

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