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Author(s):   Rao, V.S.; Skinner, G.B.
Title:   Formation of H and D atoms in pyrolysis of benzene-d6, chlorobenzene, bromobenzene, and iodobenzene behind shock waves
Journal:   J. Phys. Chem.
Volume:   92
Year:   1988
Reference type:   Journal article
Squib:   1988RAO/SKI2442

Reaction:   BromobenzenePhenyl + Br·
Reaction order:   1
Temperature:   1500 - 1900 K
Pressure:  0.41 bar
Rate expression:   1.5x1013 [s-1] e-300984 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1500 4.96E2
1525 7.36E2
1550 1.08E3
1575 1.56E3
1600 2.24E3
1625 3.17E3
1650 4.45E3
1675 6.17E3
1700 8.48E3
1725 1.15E4
1750 1.56E4
1775 2.08E4
1800 2.77E4
1825 3.64E4
1850 4.76E4
1875 6.18E4
1900 7.97E4