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Author(s):   Bedjanian, Y.
Title:   Kinetics and Products of the Reaction of OH Radicals with CINO from 220 to 940 K
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   916 - 922
Year:   2018
Reference type:   Journal article
Squib:   2018BED916-922

Reaction:   NOCl + ·OH → HONO (unspecified cis/trans isomer) + ·Cl
Reaction order:   2
Temperature:   220 - 940 K
Pressure:  2.67E-3 bar
Rate expression:   9.51x10-14 [cm3/molecule s] (T/298 K)1.74 e2045 [J/mole]/RT
Uncertainty:   1.20000005
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The uncertainty is estimated at 20%.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 1.72E-13
250 1.87E-13
300 2.18E-13
350 2.54E-13
400 2.94E-13
450 3.37E-13
500 3.83E-13
550 4.32E-13
600 4.84E-13
650 5.39E-13
700 5.97E-13
750 6.58E-13
800 7.21E-13
850 7.87E-13
900 8.55E-13
940 9.12E-13