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Author(s):   East, R.L.; Phillips, L.
Title:   Pressure-dependence of the gas-phase pyrolysis of the s-butoxyl radical at 150-190°
Journal:   J. Chem. Soc. A
Year:   1967
Reference type:   Journal article
Squib:   1967EAS/PHI1939

Reaction:   sec-C4H9NO2 + 2-C4H9O → sec-C4H9OH + C2H5COCH3 + NO
Reaction order:   2
Reference reaction:   2-C4H9O + NOC2H5COCH3 + HNO
Reference reaction order:   2
Temperature:   423 - 463 K
Pressure:  1.60E-2 - 0.27 bar
Rate expression:   4.27x101 e-16296 [J/mole]/RT
Bath gas:   sec-C4H9NO2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
423 4.15E-1
425 4.24E-1
450 5.48E-1
463 6.19E-1