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Author(s):
Whelan, C.A.; Eble, J.; Mir, Z.S.; Blitz, M.A.; Seakins, P.W.; Olzmann, M.; Stone, D.
Title:
Kinetics of the Reactions of Hydroxyl Radicals with Furan and Its Alkylated Derivatives 2-Methyl Furan and 2,5-Dimethyl Furan
Journal:
J. Phys. Chem. A
Volume:
124
Page(s):
7416 - 7426
Year:
2020
Reference type:
Journal article
Squib:
2020WHE/EBL7416-7426
Reaction:
2-Methylfuran + ·OH → Products
Reaction order:
2
Temperature:
296 - 668
K
Pressure: 5.00E-3 - 10.00 bar
Rate expression:
no rate data available
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Static or low flow - Data taken vs time
Excitation technique:
Flash photolysis (laser or conventional)
Time resolution:
In real time
Analytical technique:
Laser induced fluorescence
Comments:
Rate constants were determined over wide ranges of temperatures and pressures. However, no Arrhenius expression is provided for the experimental data.
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