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Accessibility information
Author(s):   Anson, P.C.; Fredricks, P.S.; Tedder, J.M.
Title:   Free-radical substitution in aliphatic compounds. Part I. Halogenation of n-Butane and isoButane in the gas phase
Journal:   J. Chem. Soc. A
Page(s):  
Year:   1959
Reference type:   Journal article
Squib:   1959ANS/FRE918

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1959ANS/FRE918   iso-C4H10 + Br·tert-C4H9 + HBr  419   1640              2
  Reference reaction:  iso-C4H10 + Br·iso-C4H9 + HBr 2
  1959ANS/FRE918   iso-C4H10 + ·Fiso-C4H9 + HF  298   1.39           1.39  2
  Reference reaction:  iso-C4H10 + ·Fiso-C4H9 + HF 2
  1959ANS/FRE918   iso-C4H10 + ·Cltert-C4H9 + HCl  263 - 419   2.10       -2253   5.21  2
  Reference reaction:  iso-C4H10 + ·Cliso-C4H9 + HCl 2
  1959ANS/FRE918   1-C4H10 + Br·sec-C4H9 + HBr  419   82.00              2
  Reference reaction:  1-C4H10 + Br·1-C4H9 + HBr 2
  1959ANS/FRE918   1-C4H10 + ·Fsec-C4H9 + HF  298 - 459   1.10       -399   1.29  2
  Reference reaction:  1-C4H10 + ·F1-C4H9 + HF 2
  1959ANS/FRE918   1-C4H10 + ·Clsec-C4H9 + HCl  263 - 419   1.80       -2004   4.04  2
  Reference reaction:  1-C4H10 + ·Cl1-C4H9 + HCl 2

Search returned 6 records.