Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Liu, D.; Khaled, F.; Giri, B.R.; Assaf, E.; Fittschen, C.; Farooq, A.
Title:   H-Abstraction by OH from Large Branched Alkanes: Overall Rate Measurements and Site-Specific Tertiary Rate Calculations
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   927 - 937
Year:   2017
Reference type:   Journal article
Squib:   2017LIU/KHA927-937

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2017LIU/KHA927-937   2-Methyl-3-ethylpentane + ·OH → Other Products + H2O  994 - 1357   3.07E-10       1.93E04      2
  2017LIU/KHA927-937   2,3-Dimethylpentane + ·OH → Other Products + H2O  979 - 1294   3.04E-10       1.97E04      2
  2017LIU/KHA927-937   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  1001 - 1350   5.35E-10       2.57E04      2
  2017LIU/KHA927-937   2,2,3-Trimethylpentane + ·OH → Other Products + H2O  850 - 1316   4.58E-10       2.30E04      2
  2017LIU/KHA927-937   2,3,4-Trimethylpentane + ·OH → Other Products + H2O  971 - 1428   3.74E-10       2.09E04      2
  2017LIU/KHA927-937   3-Ethylpentane + ·OH → Other Products + H2O  1010 - 1392   2.63E-10       1.72E04      2
  2017LIU/KHA927-937   2,2,3,4-Tetramethylpentane + ·OH → Other Products + H2O  941 - 1276   4.65E-10       2.40E04      2
  2017LIU/KHA927-937   ·OH + 2,2-Dimethyl-3-ethylpentane → Other Products + H2O  948 - 1364   9.10E-10       2.85E04      2
  2017LIU/KHA927-937   2,4-Dimethyl-3-ethylpentane + ·OH → Other Products + H2O  933 - 1422   3.45E-10       1.90E04      2
  2017LIU/KHA927-937   2-Methyl-3-ethylpentane + ·OH → Other Products + H2O  294   7.55E-12              2
  2017LIU/KHA927-937   2,2,3-Trimethylpentane + ·OH → Other Products + H2O  294   5.54E-12              2
  2017LIU/KHA927-937   3-Ethylpentane + ·OH → Other Products + H2O  294   6.32E-12              2
  2017LIU/KHA927-937   2,2,3,4-Tetramethylpentane + ·OH → Other Products + H2O  294   5.44E-12              2
  2017LIU/KHA927-937   ·OH + 2,2-Dimethyl-3-ethylpentane → Other Products + H2O  294   5.77E-12              2
  2017LIU/KHA927-937   2,4-Dimethyl-3-ethylpentane + ·OH → Other Products + H2O  294   8.66E-12              2
  2017LIU/KHA927-937   2,3-Dimethylpentane + ·OH → Other Products + H2O  287 - 1294   3.95E-13   2.82   -7084   6.89E-12  2
  2017LIU/KHA927-937   2,2,3-Trimethylbutane + ·OH → Other Products + H2O  296 - 1350   1.46E-13   3.45   -8481   4.49E-12  2
  2017LIU/KHA927-937   2,2,3-Trimethylpentane + ·OH → Other Products + H2O  294 - 1316   1.57E-13   3.48   -8497   4.84E-12  2
  2017LIU/KHA927-937   2,3,4-Trimethylpentane + ·OH → Other Products + H2O  294 - 1428   3.26E-13   3.04   -7417   6.51E-12  2
  2017LIU/KHA927-937   3-Ethylpentane + ·OH → Other Products + H2O  294 - 1392   1.88E-12   2.10   -3093   6.56E-12  2
  2017LIU/KHA927-937   2,2,3,4-Tetramethylpentane + ·OH → Other Products + H2O  294 - 1276   2.25E-13   3.20   -7816   5.27E-12  2
  2017LIU/KHA927-937   ·OH + 2,2-Dimethyl-3-ethylpentane → Other Products + H2O  294 - 1364   1.74E-13   3.46   -8464   5.29E-12  2
  2017LIU/KHA927-937   2,4-Dimethyl-3-ethylpentane + ·OH → Other Products + H2O  294 - 1422   3.83E-13   2.96   -7441   7.73E-12  2

Search returned 23 records.