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Author(s):   Garcia Dominguez, J.A.; Kerr, J.A.; Trotman-Dickenson, A.F.
Title:   The reactions of alkyl radicals. Part X. The disproportionation of ethyl, isopropyl, and t-butyl radicals
Journal:   J. Chem. Soc. London
Volume:   66
Page(s):   3357 - 3360
Year:   1962
Reference type:   Journal article
Squib:   1962GAR/KER3357-3360

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1962GAR/KER3357-3360   tert-C4H9 + tert-C4H9iso-C4H10 + Isobutene  323 - 352   3.19              2
  Reference reaction:  tert-C4H9 + tert-C4H92,2,3,3-Tetramethylbutane 2
  1962GAR/KER3357-3360   tert-C4H9 + 2-C3H7C3H8 + Isobutene  345 - 355   0.70              2
  Reference reaction:  tert-C4H9 + 2-C3H72,2,3-Trimethylbutane 2
  1962GAR/KER3357-3360   tert-C4H9 + 2-C3H7iso-C4H10 + CH3CH=CH2  346 - 352   0.67              2
  Reference reaction:  tert-C4H9 + 2-C3H72,2,3-Trimethylbutane 2
  1962GAR/KER3357-3360   tert-C4H9 + ·C2H5C2H6 + Isobutene  347 - 353   0.48              2
  Reference reaction:  tert-C4H9 + ·C2H5(CH3)3CCH2CH3 2
  1962GAR/KER3357-3360   tert-C4H9 + ·C2H5C2H4 + iso-C4H10  347 - 353   0.31              2
  Reference reaction:  tert-C4H9 + ·C2H5(CH3)3CCH2CH3 2
  1962GAR/KER3357-3360   2-C3H7 + ·C2H5C2H6 + CH3CH=CH2  321 - 385   0.43              2
  Reference reaction:  2-C3H7 + ·C2H5iso-C5H12 2
  1962GAR/KER3357-3360   2-C3H7 + ·C2H5C2H4 + C3H8  321 - 385   0.19              2
  Reference reaction:  2-C3H7 + ·C2H5iso-C5H12 2

Search returned 7 records.