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Accessibility information
Author(s):   Heydtmann, H.; Rinck, G.
Title:   Die Kinetik des thermischen Zerfalls von 2-Chlorbutan in der Gasphase
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   30
Page(s):   250 - 261
Year:   1961
Reference type:   Journal article
Squib:   1961HEY/RIN250-261

Reaction:   sec-C4H9Cl(E)-2-C4H8 + HCl
Reaction order:   1
Temperature:   589 - 666 K
Pressure:  6.67E-3 - 0.59 bar
Rate expression:   3.73x1013 [s-1] e-212019 [±2120 J/mole]/RT
Bath gas:   sec-C4H9Cl
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
589 5.88E-6
600 1.30E-5
625 7.12E-5
650 3.42E-4
666 8.78E-4