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Author(s):   Tsang, W.; Hampson, R.F.
Title:   Chemical kinetic data base for combustion chemistry. Part I. Methane and related compounds
Journal:   J. Phys. Chem. Ref. Data
Volume:   15
Year:   1986
Reference type:   Journal article
Squib:   1986TSA/HAM1087

Reaction:   CH4·CH3 +
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   3.72x1015 [s-1] e-434015 [J/mole]/RT
Uncertainty:   1.5
Bath gas:   N2
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 1.01E-60
400 7.85E-42
500 1.70E-30
600 6.12E-23
700 1.53E-17
800 1.71E-13
900 2.41E-10
1000 7.95E-8
1100 9.15E-6
1200 4.77E-4
1300 1.36E-2
1400 2.39E-1
1500 2.86E0
1600 2.52E1
1700 1.72E2
1800 9.46E2
1900 4.35E3
2000 1.72E4
2100 5.96E4
2200 1.84E5
2300 5.18E5
2400 1.33E6
2500 3.18E6