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Author(s):   Zhao, Z.; Stickel, R.E.; Wine, P.H.
Title:   Branching ratios for methyl elimination in the reactions of OD radicals and Cl atoms with CH3SCH3
Journal:   Chem. Phys. Lett.
Volume:   251
Page(s):   59 - 66
Year:   1996
Reference type:   Journal article
Squib:   1996ZHA/STI59-66

Reaction:   (CH3)2S + ·Cl·CH3 + CH3SCl
Reaction order:   2
Reference reaction:   (CH3)2S + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.93 bar
Rate expression:   2.0x10-2
Rate constant is an upper limit.
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

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