Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kerr, J.A.; Smith, B.J.A.; Trotman-Dickenson, A.F.; Young, J.C.
Title:   The abstraction of halogen atoms from alkyl halides by the trichlorosilyl radical
Journal:   J. Chem. Soc. A
Page(s):   510 - 513
Year:   1968
Reference type:   Journal article
Squib:   1968KER/SMI510-513

Reaction:   sec-C4H9Cl + SiCl3sec-C4H9 + SiCl4
Reaction order:   2
Reference reaction:   CH3Cl + SiCl3·CH3 + SiCl4
Reference reaction order:   2
Temperature:   373 - 573 K
Rate expression:   1.82 e8314 [J/mole]/RT
Bath gas:   SiHCl3
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Other (direct)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
373 2.66E1
375 2.62E1
400 2.22E1
425 1.91E1
450 1.68E1
475 1.49E1
500 1.34E1
525 1.22E1
550 1.12E1
573 1.04E1