Kinetics Database Logo     Home
©NIST, 2022
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article



Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Holmes, J.L.; Kutschke, K.O.
Title:   Reactions of trifluoromethyl radicals with benzene and toluene
Journal:   Trans. Faraday Soc.
Volume:   58
Year:   1962
Reference type:   Journal article
Squib:   1962HOL/KUT333

Reaction:   iso-C4H10 + ·CF3CHF3 + tert-C4H9
Reaction order:   2
Reference reaction:   Benzene + ·CF3 → Adduct
Reference reaction order:   2
Temperature:   300 - 383 K
Rate expression:   5.13x101 e-1621 [±8314472 J/mole]/RT
Uncertainty:   1.50999999
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
300 2.68E1
325 2.82E1
350 2.94E1
375 3.05E1
383 3.08E1