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Author(s):   Braun, W.; Bass, A.M.; Pilling, M.
Title:   Flash photolysis of ketone and diazomethane: The production and reaction kinetics of triplet and singlet methylene
Journal:   J. Chem. Phys.
Volume:   52
Year:   1970
Reference type:   Journal article
Squib:   1970BRA/BAS5131

Reaction:   ·CH2 + ·CH2C2H2 + H2
Reaction order:   2
Temperature:   298 K
Pressure:  1.31E-3 - 2.13E-2 bar
Rate expression:   5.3x10-11 [±1.48x10-11 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

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