Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Middala, S.; Campbell, S.; Olea, C.; Scruggs, A.; Hasson, A.S.
Title:   Kinetics and Mechanism of the Reaction of Propylene Oxide with Chlorine Atoms and Hydroxy Radicals
Journal:   Int. J. Chem. Kinet.
Volume:   43
Page(s):   507 - 521
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011MID/CAM507-521

Reaction:   Methyloxirane + ·Cl → Products
Reaction order:   2
Reference reaction:   CH3OH + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   4.9x10-1±2.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Reported uncertainty is are 95% confidence limits for the slopes of the relative rates plot.

View full bibliographic record.