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Author(s):   Middala, S.; Campbell, S.; Olea, C.; Scruggs, A.; Hasson, A.S.
Title:   Kinetics and Mechanism of the Reaction of Propylene Oxide with Chlorine Atoms and Hydroxy Radicals
Journal:   Int. J. Chem. Kinet.
Volume:   43
Page(s):   507 - 521
Year:   2011
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2011MID/CAM507-521

Reaction:   Methyloxirane + ·Cl → Products
Reaction order:   2
Reference reaction:   CH3OH + ·Cl → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   4.9x10-1±2.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Reported uncertainty is are 95% confidence limits for the slopes of the relative rates plot.

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