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Author(s):   Wickramaaratchi, M.A.; Setser, D.W.; Hildebrandt, H.; Korbitzer, B.; Heydtmann, H.
Title:   Evaluation of HF product distributions deduced from infrared chemiluminescence.II. F atoms reactions
Journal:   Chem. Phys.
Volume:   94
Page(s):  
Year:   1985
Reference type:   Journal article
Squib:   1985WIC/SET109

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1985WIC/SET109   CHCl3 + ·F·CCl3 + HF  298   0.02           0.02  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1985WIC/SET109   CH3Cl + ·F·CH2Cl + HF  298   0.31           0.31  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1985WIC/SET109   CH2Cl2 + ·FCHCl2 + HF  298   0.08           0.08  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1985WIC/SET109   CD4 + ·FCD3 + DF  298   0.73           0.73  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1985WIC/SET109   CH3OD + ·FCH3 + DF  298   2.61E-11           2.61E-11  2
  1985WIC/SET109   CH3OD + ·FHF + CH2OD  298   4.30E-11           4.30E-11  2
  1985WIC/SET109   CD2Cl2 + ·FDF + CDCl2  298   0.07           0.07  2
  Reference reaction:  CH4 + ·F·CH3 + HF 2
  1985WIC/SET109   CD3OH + ·FCD3O + HF  298   4.80E-11           4.80E-11  2
  1985WIC/SET109   CD3OH + ·FDF + CD2OH  298   2.81E-11           2.81E-11  2

Search returned 9 records.