Author(s):   Wickramaaratchi, M.A.; Setser, D.W.; Hildebrandt, H.; Korbitzer, B.; Heydtmann, H.
Title:   Evaluation of HF product distributions deduced from infrared chemiluminescence.II. F atoms reactions
Journal:   Chem. Phys.
Volume:   94
Page(s):
Year:   1985
Reference type:   Journal article
Squib:   1985WIC/SET109

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |

Squib	Reaction	Temp [K]	A	k(298.00 K)	Order
1985WIC/SET109	CHCl₃ + ·F → ·CCl₃ + HF	298	0.02	0.02	2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1985WIC/SET109	CH₃Cl + ·F → ·CH₂Cl + HF	298	0.31	0.31	2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1985WIC/SET109	CH₂Cl₂ + ·F → CHCl₂ + HF	298	0.08	0.08	2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1985WIC/SET109	CD₄ + ·F → CD₃ + DF	298	0.73	0.73	2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1985WIC/SET109	CH₃OD + ·F → CH₃O· + DF	298	2.61E-11	2.61E-11	2
1985WIC/SET109	CH₃OD + ·F → HF + CH₂OD	298	4.30E-11	4.30E-11	2
1985WIC/SET109	CD₂Cl₂ + ·F → DF + CDCl₂	298	0.07	0.07	2
Reference reaction: CH₄ + ·F → ·CH₃ + HF				2
1985WIC/SET109	CD₃OH + ·F → CD₃O + HF	298	4.80E-11	4.80E-11	2
1985WIC/SET109	CD₃OH + ·F → DF + CD₂OH	298	2.81E-11	2.81E-11	2

Search returned 9 records.