Kinetics Database Logo     Home
©NIST, 2023
Accessibility information
Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Contact Us to Submit an Article

Citation

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

DOC home page

NIST home page

MML home page

Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Warnatz, J.
Title:   Rate coefficients in the C/H/O system
Page(s):  
Year:   1984
Book Title:   Combustion Chemistry
Publisher address:   ed. W.C. Gardiner,Jr., pub. Springer-Verlag,NY
Reference type:   Book Chapter
Squib:   1984WAR197C

Reaction:   sec-C4H9CH3CH=CH2 + ·CH3
Reaction order:   1
Temperature:   500 - 2000 K
Rate expression:   2.3x1014 [s-1] e-137189 [J/mole]/RT
Uncertainty:   2.0
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
500 1.07E0
600 2.62E2
700 1.33E4
800 2.54E5
900 2.51E6
1000 1.57E7
1100 7.04E7
1200 2.46E8
1300 7.07E8
1400 1.75E9
1500 3.84E9
1600 7.64E9
1700 1.40E10
1800 2.40E10
1900 3.89E10
2000 6.01E10