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Title: Kinetics of the Thermal Gas-phase Decomposition of 1,2-Epoxybutane
Journal: J. Chem. Soc. Faraday Trans. 1
Volume: 71
Page(s):
Year: 1975
Reference type: Journal article
Squib: 1975FLO/PEN851
Reaction:
Ethyloxirane → CH3CH2CH2CHO
Reaction order:
1
Temperature:
674 - 730
K
Pressure: 6.67E-3 - 9.33E-2 bar
Rate expression:
8.91x1013 [s-1] e-238625 [±4764 J/mole]/RT
Uncertainty:
2.56999993
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 674 | 2.86E-5 |
| 675 | 3.05E-5 |
| 700 | 1.39E-4 |
| 725 | 5.73E-4 |
| 730 | 7.51E-4 |