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Title: Reactions of oxygenated radicals in the gas phase. Part 14. Reactions of t-butylperoxyl radicals
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1984
Reference type: Journal article
Squib: 1984OSB/WAD1861
Reaction:
tert-C4H9 + tert-C4H9 → iso-C4H10 + Isobutene
Reaction order:
2
Reference reaction:
tert-C4H9 + tert-C4H9 → 2,2,3,3-Tetramethylbutane
Reference reaction order:
2
Temperature:
343 - 453
K
Pressure: 0.27 bar
Rate expression:
2.67±1.9x10-1
Bath gas:
N2
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Direct photolysis
Analytical technique:
Gas chromatography
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