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Author(s):   Takayanagi, T.; Kurosaki, Y.; Misawa, K.; Sugiura, M.; Kobayashi, Y.; Sato, K.; Tsunashima, S.
Title:   Measurements of Thermal Rate Constants and Theoretical Calculations for the N(2D, 2P) + C2H2 and C2D2 Reactions
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   6251 - 6258
Year:   1998
Reference type:   Journal article
Squib:   1998TAK/KUR6251-6258

Reaction:   N(2P) + C2H2 → Products
Reaction order:   2
Temperature:   220 - 293 K
Pressure:  0.93 bar
Rate expression:   1.0x10-10 [±1.0x10-11 cm3/molecule s] e-3682 [±251 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Radiolysis
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 1.34E-11
225 1.40E-11
250 1.70E-11
275 2.00E-11
293 2.21E-11