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Author(s):   Vijayakumar, S.; Ramya, C.B.; Kumar, A.; Rajakumar, B.
Title:   Kinetic investigations of Cl atom initiated photo-oxidation reactions of cyclic unsaturated hydrocarbons in the gas phase: an experimental and theoretical study
Journal:   New J. Chem.
Volume:   41
Page(s):   7491 - 7505
Year:   2017
Reference type:   Journal article
Squib:   2017VIJ/RAM7491-7505

Reaction:   (Z)-Cycloheptene + ·Cl → Products
Reaction order:   2
Temperature:   280 - 360 K
Pressure:  1.01 bar
Rate expression:   3.42x10-11 [±2.9x10-11 cm3/molecule s] e6876 [±2228 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   1,3-Butadiene and isoprene were used as reference compounds.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
280 6.56E-10
300 5.39E-10
325 4.36E-10
350 3.63E-10
360 3.40E-10