Author(s):   Vereecken, L.; Peeters, J.
Title:   Reactions of chemically activated C₉H₉ species II: The reaction of phenyl radicals with allene and cyclopropene, and of benzyl radicals with acetylene
Journal:   Phys. Chem. Chem. Phys.
Volume:   5
Page(s):   2807 - 2817
Year:   2003
Reference type:   Journal article
Squib:   2003VER/PEE2807-2817

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	n	Ea [J/mole]	k(298.00 K)	Order
2003VER/PEE2807-2817	CH₂=C=CH₂ + Phenyl → Products	200 - 2000	6.66E-14	3.19	1.17E04	6.02E-16	2
2003VER/PEE2807-2817	C₂H₂ + Benzyl → Products	200 - 2000	1.21E-13	1.84	5.18E04	9.99E-23	2
2003VER/PEE2807-2817	C₂H₂ + Benzyl → Products	200 - 2000	2.34E-18	4.71	5930	2.13E-19	2
2003VER/PEE2807-2817	Phenyl + Cyclopropene → Products	200 - 2000	3.88E-14	3.25	-650	5.05E-14	2
2003VER/PEE2807-2817	Phenyl + Cyclopropene → 2-Phenylcyclopropenyl	200 - 2000	9.11E-14	2.57	1380	5.22E-14	2
2003VER/PEE2807-2817	Phenyl + Cyclopropene → Benzene + Cycloprop-1-enyl	200 - 2000	5.48E-14	3.13	2.99E04	3.17E-19	2
2003VER/PEE2807-2817	Phenyl + Cyclopropene → Benzene + Cyclopropenyl radical	200 - 2000	3.59E-14	3.20	1.52E04	7.65E-17	2
2003VER/PEE2807-2817	CH₂=C=CH₂ + Phenyl → C₆H₅CH₂C(·)=CH₂	200 - 2000	5.40E-14	2.53	1.19E04	4.40E-16	2
2003VER/PEE2807-2817	CH₂=C=CH₂ + Phenyl → C₆H₅C(=CH₂)CH₂(·)	200 - 2000	7.45E-14	2.64	1.56E04	1.40E-16	2
2003VER/PEE2807-2817	CH₂=C=CH₂ + Phenyl → Benzene + ·CH₂C≡CH	200 - 2000	4.67E-14	3.20	1.82E04	3.04E-17	2
2003VER/PEE2807-2817	Benzene + C₂H₂ → C₆H₅CH₂CH=CH(·)	200 - 2000	1.21E-13	1.84	5.18E04	9.99E-23	2

Search returned 11 records.