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Author(s):   White, M.L.; Kuntz, R.R.
Title:   Rotating sector study of the gas phase photolysis of the carbon tetrachloride-cyclohexane system
Journal:   Int. J. Chem. Kinet.
Volume:   3
Page(s):   127 - 136
Year:   1971
Reference type:   Journal article
Squib:   1971WHI/KUN127-136

Reaction:   Cyclohexane + ·CCl3CHCl3 + Cyclohexyl
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3CCl3CCl3
Temperature:   385 - 456 K
Rate expression:   1.02x10-12 [cm3/molecule s] e-44732 [J/mole]/RT
Bath gas:   CCl4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
385 8.74E-19
400 1.48E-18
425 3.26E-18
450 6.58E-18
456 7.70E-18