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Chemical Sciences Division

Applied Chemicals and Materials Division

Author(s):   Currie, J.; Sidebottom, H.; Tedder, J.
Title:   The reaction of cyclohexyl radicals with carbon tetrachloride
Journal:   Int. J. Chem. Kinet.
Volume:   6
Page(s):  
Year:   1974
Reference type:   Journal article
Squib:   1974CUR/SID481

Reaction:   Cyclohexane + ·CCl3CHCl3 + Cyclohexyl
Reaction order:   2
Reference reaction:   ·CCl3 + ·CCl3 → Products
Temperature:   303 - 673 K
Rate expression:   1.2x10-12 [cm3/molecule s] e-41822 [±4182 J/mole]/RT
Uncertainty:   1.35000002
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
303 7.42E-20
325 2.28E-19
350 6.90E-19
375 1.80E-18
400 4.16E-18
425 8.71E-18
450 1.68E-17
475 3.03E-17
500 5.14E-17
525 8.30E-17
550 1.28E-16
575 1.91E-16
600 2.75E-16
625 3.84E-16
650 5.24E-16
673 6.82E-16