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Title: Pyrolysis of acrylonitrile at elevated temperatures. Studies with a single-pulse shock tube
Journal: J. Phys. Chem.
Volume: 93
Page(s): 1369 - 1373
Year: 1989
Reference type: Journal article
Squib: 1989LIF/BID1369-1373
Reaction:
CH2CHCN → H· + CH2=C(CN)
Reaction order:
1
Temperature:
1150 - 1430
K
Pressure: 3.24 bar
Rate expression:
2.51x1013 [s-1] e-321770 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 1150 | 6.09E-2 |
| 1175 | 1.25E-1 |
| 1200 | 2.48E-1 |
| 1225 | 4.78E-1 |
| 1250 | 8.99E-1 |
| 1275 | 1.65E0 |
| 1300 | 2.96E0 |
| 1325 | 5.19E0 |
| 1350 | 8.91E0 |
| 1375 | 1.50E1 |
| 1400 | 2.48E1 |
| 1425 | 4.03E1 |
| 1430 | 4.43E1 |