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Author(s):   Lifshitz, A.; Bidani, M.; Suslensky, A.; Tamburu, C.
Title:   Pyrolysis of acrylonitrile at elevated temperatures. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1369 - 1373
Year:   1989
Reference type:   Journal article
Squib:   1989LIF/BID1369-1373

Reaction:   CH2CHCN + CH2=C(CN)
Reaction order:   1
Temperature:   1150 - 1430 K
Pressure:  3.24 bar
Rate expression:   2.51x1013 [s-1] e-321770 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1150 6.09E-2
1175 1.25E-1
1200 2.48E-1
1225 4.78E-1
1250 8.99E-1
1275 1.65E0
1300 2.96E0
1325 5.19E0
1350 8.91E0
1375 1.50E1
1400 2.48E1
1425 4.03E1
1430 4.43E1