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Title: The nitric oxide-catalyzed recombination of chlorine atoms
Journal: Chem. Commun.
Page(s): 287 - 289
Year: 1966
Reference type: Journal article
Squib: 1966CLA/CLY287-289
Reaction:
NO + ·Cl → NOCl
Reaction order:
3
Temperature:
270 - 620
K
Pressure: 9.33E-4 - 2.67E-3 bar
Rate expression:
1.23x10-32 [cm6/molecule2 s] e5014 [±856 J/mole]/RT
Bath gas:
SF6
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Vis-UV emission
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm6/molecule2 s] |
|---|---|
| 270 | 1.15E-31 |
| 275 | 1.10E-31 |
| 300 | 9.18E-32 |
| 325 | 7.86E-32 |
| 350 | 6.89E-32 |
| 375 | 6.14E-32 |
| 400 | 5.55E-32 |
| 425 | 5.08E-32 |
| 450 | 4.70E-32 |
| 475 | 4.38E-32 |
| 500 | 4.11E-32 |
| 525 | 3.88E-32 |
| 550 | 3.68E-32 |
| 575 | 3.51E-32 |
| 600 | 3.36E-32 |
| 620 | 3.25E-32 |