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 Author(s):   Atkinson, R.; Baulch, D.L.; Cox, R.A.; Crowley, J.N.; Hampson, R.F, Jr.; Kerr, J.A.; Rossi, M.J.; Troe, J.
Title:   Summary of Evaluated Kinetic and Photochemical Data for Atmospheric Chemistry
Journal:   Not in System
Page(s):   1 - 56
Year:   2001
Comments:   IUPAC Subcommittee on Gas Kinetic Data Evaluation for Atmospheric ChemistryWeb Version December 2001
Reference type:   Journal article
Squib:   2001ATK/BAU1-56

Reaction:   (CH3)2CHO2 + (CH3)2CHO2 → (CH3)2CHO· + (CH3)2CHO· + O2
Reaction order:   2
Temperature:   300 - 400 K
Rate expression:   2.0x10-15 [cm3/molecule s] e-3159 [J/mole]/RT
Category:  Review
Data type:   Extensive literature review
Pressure dependence:   None reported

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 5.64E-16
325 6.21E-16
350 6.75E-16
375 7.26E-16
400 7.73E-16