Author(s):   Kaufman, E.D.; Reed, J.F.
Title:   The vapor phase diffusion flame reaction of sodium with fluorinated chloromethanes
Journal:   J. Chem. Phys.
Volume:   67
Page(s):
Year:   1963
Reference type:   Journal article
Squib:   1963KAU/REE896

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	Order
1963KAU/REE896	CCl₄ + Na → ·CCl₃ + NaCl	519 - 583	3.49E-09	3.52E04	2
1963KAU/REE896	CCl₄ + Na → ·CCl₃ + NaCl	583	2.47E-12		2
1963KAU/REE896	CFCl₃ + Na → ·CCl₂F + NaCl	519 - 583	1.88E-09	3.64E04	2
1963KAU/REE896	CFCl₃ + Na → ·CCl₂F + NaCl	583	1.27E-12		2
1963KAU/REE896	CF₂Cl₂ + Na → ·CClF₂ + NaCl	519 - 583	1.53E-09	3.77E04	2
1963KAU/REE896	CF₂Cl₂ + Na → ·CClF₂ + NaCl	583	6.48E-13		2
1963KAU/REE896	CF₃Cl + Na → ·CF₃ + NaCl	519 - 583	8.63E-10	4.27E04	2
1963KAU/REE896	CF₃Cl + Na → ·CF₃ + NaCl	583	1.30E-13		2

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