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Author(s):   Tsang, W.
Title:   Chemical kinetic data base for combustion chemistry. Part 4. Isobutane
Journal:   J. Phys. Chem. Ref. Data
Volume:   19
Page(s):   1 - 68
Year:   1990
Reference type:   Journal article
Squib:   1990TSA1-68

Reaction:   iso-C4H9CH3CH=CH2 + ·CH3
Reaction order:   1
Temperature:   300 - 2500 K
Rate expression:   2.0x1013 [s-1] e-125549 [J/mole]/RT
Uncertainty:   5.0
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 2.76E-9
400 8.06E-4
500 1.53E0
600 2.35E2
700 8.56E3
800 1.27E5
900 1.03E6
1000 5.54E6
1100 2.18E7
1200 6.86E7
1300 1.81E8
1400 4.14E8
1500 8.49E8
1600 1.59E9
1700 2.78E9
1800 4.55E9
1900 7.07E9
2000 1.05E10
2100 1.51E10
2200 2.09E10
2300 2.82E10
2400 3.70E10
2500 4.76E10