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Accessibility information
Author(s):   Avramenko, L.I.; Krasnen'kov, V.M.
Title:   Reactions of nitrogen atoms report 3. Rate constant and mechanism of the elementary reaction of nitrogen atoms with acetylene
Journal:   Bull. Acad. Sci. USSR Div. Chem. Sci. (Engl. Transl.)
Page(s):   770 - 773
Year:   1964
Reference type:   Journal article
Squib:   1964AVR/KRA770-773

Reaction:   C2H2 + N → Products
Reaction order:   2
Temperature:   291 - 523 K
Pressure:  6.40E-3 bar
Rate expression:   1.62x102 [cm3/molecule s] (T/298 K)0.50 e-9645 [±8314472 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Other (direct)

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
291 2.96E0
300 3.39E0
325 4.75E0
350 6.37E0
375 8.22E0
400 1.03E1
425 1.26E1
450 1.51E1
475 1.77E1
500 2.06E1
523 2.33E1