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Author(s):   Oksdath-Mansilla, G.; Penenory, A.B.; Albu, M.; Barnes, I.; Wiesen, P.; Teruel, M.A.
Title:   FTIR relative kinetic study of the reactions of CH3CH2SCH2CH3 and CH3CH2SCH3 with OH radicals and Cl atoms at atmospheric pressure
Journal:   Chem. Phys. Lett.
Volume:   477
Page(s):   22 - 27
Year:   2009
Reference type:   Journal article
Squib:   2009OKS/PEN22-27

Reaction:   C2H5SCH3 + ·Cl → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   3.06x10-10 [±4.2x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Nitrogen and air were used as bath gases; isobutene and propene were used as reference compounds. The error quoted for the rate constant is a combination of the 2σ statistical error from the linear regression analysis and a 20% error allocated to the potential errors in the recommended values of the rate coefficients for the reference reactions.

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