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Author(s):   Lesclaux, R.; Dognon, A.M.; Caralp, F.
Title:   Photo-oxidation of halomethanes at low temperature: The decomposition rate of CCl3O and CFCl2O radicals
Journal:   J. Photochem. Photobiol. A
Volume:   41
Page(s):  
Year:   1987
Reference type:   Journal article
Squib:   1987LES/DOG1

Reaction:   CCl3O → COCl2 + ·Cl
Reaction order:   1
Reference reaction:   NO + CCl3O → Products
Reference reaction order:   2
Temperature:   233 K
Pressure:  9.33E-3 bar
Rate expression:   1.0x1016 [molecule/cm3]
Rate constant is a lower limit.
Bath gas:   CCl3O
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Sensitized photolysis
Analytical technique:   Mass spectrometry

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