Author(s):   Stothard, N.D.; Walker, R.W.
Title:   Arrhenius parameters for the addition of HO₂ radicals to (E)-but-2-ene over the range 400-520°C
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   86
Page(s):
Year:   1990
Reference type:   Journal article
Squib:   1990STO/WAL2115

Associated entries:

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Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

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Squib	Reaction	Temp [K]	A	Ea [J/mole]	k(298.00 K)	Order
1990STO/WAL2115	(E)-2-C₄H₈ + HO₂ → 2,2-dimethyloxirane + ·OH	673 - 793	6.76E-13	5.00E04		2
1990STO/WAL2115	(E)-2-C₄H₈ + HO₂ → 2,2-dimethyloxirane + ·OH	673 - 793	0.40	-1.26E04		2
Reference reaction: CH₃CH=CH₂ + HO₂ → Methyloxirane + ·OH					2

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