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Author(s):   Ayhens, Y.V.; Nicovich, J.M.; McKee, M.L.; Wine, P.H.
Title:   Kinetic and mechanistic study of the reaction of atomic chlorine with methyl iodide over the temperature range 218-694 K
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   9382 - 9390
Year:   1997
Reference type:   Journal article
Squib:   1997AYH/NIC9382-9390

Reaction:   CH3I + ·ClHCl + ·CH2I
Reaction order:   2
Temperature:   364 - 694 K
Pressure:  6.67E-3 - 0.67 bar
Rate expression:   5.43x10-11 [±1.2x10-11 cm3/molecule s] e-10393 [±831 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
364 1.75E-12
375 1.94E-12
400 2.39E-12
425 2.87E-12
450 3.38E-12
475 3.91E-12
500 4.46E-12
525 5.02E-12
550 5.59E-12
575 6.18E-12
600 6.76E-12
625 7.35E-12
650 7.94E-12
675 8.52E-12
694 8.97E-12