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Author(s):   Garrett, B.C.; Truhlar, D.G.
Title:   Generalized transition state theory. Canonical variational calculations using the bond energy-bond order method for bimolecular reactions of combustion products
Journal:   J. Am. Chem. Soc.
Volume:   101
Page(s):  
Year:   1979
Reference type:   Journal article
Squib:   1979GAR/TRU5207

Reaction:   CF + ·FC + F2
Reaction order:   2
Temperature:   300 - 1000 K
Rate expression:   1.06x10-10 [cm3/molecule s] e-299321 [J/mole]/RT
Category:  Theory
Data type:   Bond energy-bond order (BEBO)

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 8.12E-63
350 2.26E-55
400 8.68E-50
450 1.91E-45
500 5.70E-42
550 3.97E-39
600 9.28E-37
650 9.37E-35
700 4.90E-33
750 1.51E-31
800 3.03E-30
850 4.28E-29
900 4.50E-28
950 3.69E-27
1000 2.46E-26