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Title: Mechanism of the pyrolysis of bicyclo[2.2.1]heptadiene. Kinetics of the bicyclo[2.2.1]heptadiene to toluene isomerization
Journal: J. Am. Chem. Soc.
Volume: 86
Page(s):
Year: 1964
Reference type: Journal article
Squib: 1964HER/LOW1922
Reaction:
1,3,5-Cycloheptatriene → Toluene
Reaction order:
1
Temperature:
617 - 704
K
Rate expression:
7.94x1013 [s-1] e-217839 [±8314472 J/mole]/RT
Uncertainty:
1.90999997
Bath gas:
2,5-Norbornadiene
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 617 | 2.87E-5 |
| 625 | 4.95E-5 |
| 650 | 2.48E-4 |
| 675 | 1.10E-3 |
| 700 | 4.41E-3 |
| 704 | 5.46E-3 |