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Title: Unimolecular processes in vibrationally highly excited cycloheptatrienes. I. Thermal isomerization in shock waves
Journal: J. Chem. Phys.
Volume: 70
Page(s):
Year: 1979
Reference type: Journal article
Squib: 1979AST/TRO5107
Reaction:
1,3,5-Cycloheptatriene → Toluene
Reaction order:
1
Temperature:
600 - 1400
K
Pressure: 2.00E-2 - 4.93 bar
Rate expression:
1.25x1014 [s-1] e-220334 [J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
High or low pressure extrapolation
Excitation technique:
Thermal
Analytical technique:
Vis-UV absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 600 | 8.23E-6 |
| 650 | 2.46E-4 |
| 700 | 4.53E-3 |
| 750 | 5.65E-2 |
| 800 | 5.14E-1 |
| 850 | 3.61E0 |
| 900 | 2.04E1 |
| 950 | 9.60E1 |
| 1000 | 3.87E2 |
| 1050 | 1.37E3 |
| 1100 | 4.31E3 |
| 1150 | 1.23E4 |
| 1200 | 3.21E4 |
| 1250 | 7.76E4 |
| 1300 | 1.75E5 |
| 1350 | 3.73E5 |
| 1400 | 7.52E5 |