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Accessibility information
Author(s):   Roth, W.R.; Bauer, F.; Beitat, A.; Ebbrecht, T.; Wustefeld, M.
Title:   Die bildungsenthalpie des allyl- und methallyl-radikals
Journal:   Chem. Ber.
Volume:   124
Page(s):   1453 - 1460
Year:   1991
Reference type:   Journal article
Squib:   1991ROT/BAU1453-1460

Reaction:   1,3,5-Cycloheptatriene → Toluene
Reaction order:   1
Temperature:   1061 - 1171 K
Rate expression:   6.0x1013 [±6.0x1013 s-1] e-213682 [±8564 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1061 1.82E3
1075 2.49E3
1100 4.28E3
1125 7.19E3
1150 1.18E4
1171 1.77E4