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Author(s):   Maloney, K.K.; Palmer, H.B.
Title:   Low-pressure thermal decomposition of ONBr and ONCl in shock waves
Journal:   Int. J. Chem. Kinet.
Volume:   5
Page(s):   1023 - 1037
Year:   1973
Reference type:   Journal article
Squib:   1973MAL/PAL1023-1037

Reaction:   NOClNO + ·Cl
Reaction order:   2
Temperature:   938 - 1260 K
Pressure:  0.54 - 0.93 bar
Rate expression:   1.48x10-8 [cm3/molecule s] e-145503 [±8730 J/mole]/RT
Uncertainty:   2.63000011
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
938 1.17E-16
950 1.48E-16
975 2.37E-16
1000 3.72E-16
1025 5.69E-16
1050 8.55E-16
1075 1.26E-15
1100 1.82E-15
1125 2.60E-15
1150 3.64E-15
1175 5.03E-15
1200 6.87E-15
1225 9.25E-15
1250 1.23E-14
1260 1.37E-14