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Author(s):   Lifshitz, A.; Bauer, S.H.
Title:   Studies with a single-pulse shock tube. I. The cis-trans isomerization of butene-2
Journal:   J. Chem. Phys.
Volume:   38
Page(s):   2056 - 2063
Year:   1963
Reference type:   Journal article
Squib:   1963LIF/BAU2056-2063

Reaction:   (Z)-2-C4H8(E)-2-C4H8
Reaction order:   1
Temperature:   1000 - 1250 K
Pressure:  1.00E-1 - 0.29 bar
Rate expression:   3.5x1014 [s-1] e-271883 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 2.20E0
1025 4.89E0
1050 1.04E1
1075 2.15E1
1100 4.30E1
1125 8.33E1
1150 1.57E2
1175 2.87E2
1200 5.12E2
1225 8.93E2
1250 1.52E3